Kinetic studies on chromium-glycinato complexes in acidic and alkaline media
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منابع مشابه
Reduction of hypervalent chromium in acidic media by alginic acid.
Selective oxidation of carboxylate groups present in alginic acid by Cr(VI) affords CO2, oxidized alginic acid, and Cr(III) as final products. The redox reaction afforded first-order kinetics in [alginic acid], [Cr(VI)], and [H(+)], at fixed ionic strength and temperature. Kinetic studies showed that the redox reaction proceeds through a mechanism which combines Cr(VI)→Cr(IV)→Cr(II) and Cr(VI)→...
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ژورنال
عنوان ژورنال: Transition Metal Chemistry
سال: 2010
ISSN: 0340-4285,1572-901X
DOI: 10.1007/s11243-010-9431-5